Xeractinol - A new flavanonol C-glucoside from Paepalanthus argenteus var. argenteus (Bongard) Hensold (Eriocaulaceae)

New compound isolated from methanolic extract from the leaves of Paepalanthus argenteus var. argenteus (Bongard) Hensold was characterized as xeractinol, a new dihydroflavonol C-glucoside. The structure was elucidated on the basis of extensive spectroscopic analysis (1D and 2D NMR, MS, HREIMS, IR an...

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Detalhes bibliográficos
Autores: Dokkedal, Anne Ligia, Lavarda, Francisco, dos Santos, Lourdes Campaner, Vilegas, Wagner [UNESP]
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2007
País:Brasil
Recursos:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/36324
Acesso em linha:http://dx.doi.org/10.1590/S0103-50532007000200029
http://hdl.handle.net/11449/36324
Access Level:acceso abierto
Palavra-chave:Paepalanthus argenteus var. argenteus
Eriocaulaceae
dihydroflavonol
xeractinol
ab initio calculations
Descrição
Resumo:New compound isolated from methanolic extract from the leaves of Paepalanthus argenteus var. argenteus (Bongard) Hensold was characterized as xeractinol, a new dihydroflavonol C-glucoside. The structure was elucidated on the basis of extensive spectroscopic analysis (1D and 2D NMR, MS, HREIMS, IR and UV). Ab initio electronic structure calculations support our proposal to the molecular structure. The dihydroflavonol herein isolated may serve as taxonomic marker of Paepalanthus subgenus Xeractis, because this flavonoid have not been reported in any other taxon of Eriocaulaceae.