ESR STUDY OF THE COMPLEX-FORMATION BETWEEN CU(CLO4)2 AND A FUNCTIONALIZED SILICA-GEL SURFACE

The formation of the complex between Cu(ClO4)2 and a silica gel surface grafted with benzimidazole groups has been investigated by ESR. The parameters of the ESR spectrum of the complex obtained are presented and used to determine the most probable immediate environment of the complex formed on the...

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Detalhes bibliográficos
Autores: Dias, N. L., Gushikem, Y., Moreira, J. C., Polito, W. L., Rodrigues, E.
Formato: artículo
Estado:Versión publicada
Fecha de publicación:1994
País:Brasil
Recursos:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/218603
Acesso em linha:http://dx.doi.org/10.5935/0103-5053.19940009
http://hdl.handle.net/11449/218603
Access Level:acceso abierto
Palavra-chave:BENZIMIDAZOLE
FUNCTIONALIZATION OF SILICA GEL
Descrição
Resumo:The formation of the complex between Cu(ClO4)2 and a silica gel surface grafted with benzimidazole groups has been investigated by ESR. The parameters of the ESR spectrum of the complex obtained are presented and used to determine the most probable immediate environment of the complex formed on the surface of the solid phase. The fit of the theoretical expressions with the experimental data is very reasonable.