Determinação eletroquímica do pesticida parationa metílica em águas de reservatório por voltametria de redissolução catódica

Methyl parathion is an organophosphorus compound widely used in Brazilian agriculture as antifouling agent. Given its importance, this paper presents the development and application of an electrochemical method for determination of the compound in natural waters. Results obtained during an initial o...

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Detalhes bibliográficos
Autores: Barbosa, Silvanito Alves, Santos, Renê Humberto Tavares, Souza, Michel Rafael dos Santos, Garcia, Carlos Alexandre Borges, Alves, Jose do Patrocinio Hora, Arguelho, Maria de Lara Palmeira de Macedo
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2011
País:Brasil
Recursos:Universidade Federal de Sergipe (UFS)
Repositorio:Repositório Institucional da UFS
Idioma:portugués
OAI Identifier:oai:oai:ri.ufs.br:repo_01:riufs/1808
Acesso em linha:https://ri.ufs.br/handle/riufs/1808
Access Level:acceso abierto
Palavra-chave:Química
Metil paration
Pesticida
Análise eletrolítica
Methyl parathion
Pesticide
Electroanalysis
Descrição
Resumo:Methyl parathion is an organophosphorus compound widely used in Brazilian agriculture as antifouling agent. Given its importance, this paper presents the development and application of an electrochemical method for determination of the compound in natural waters. Results obtained during an initial optimization stage demonstrated the suitability of the technique for trace analysis, with limits of detection and quantification of 1.3 µg L-1 and 4.3 µg L-1, respectively. Samples were collected from the Jabiberi River (Tobias Barreto, State of Sergipe) and were shown to contain methyl parathion concentrations of 96.9 µg L-1 (location 1) and 34.7 µg L-1 (location 2). These measurements are indicative of levels of contamination above those permitted by Brazilian legislation (CONAMA). Hence, in addition to assisting in the validation of the electroanalytical method as a tool for pesticide analysis, the results highlight the need for regulation and control of pesticide levels in natural waters.