Geoquímica inorgânica e orgânica dos folhelhos da Formação Pimenteiras: implicações para um sistema petrolífero não convencional

The Pimenteiras Formation records the marine ingression in the Meso/Neo-Devonian of the Parnaíba Basin, and it shales are the main source rock interval for its conventional petroleum system. The aim of this paper is to integrate geological and geochemical data in order to provide the potential on sh...

Descripción completa

Detalles Bibliográficos
Autores: Souza, Ana Clara Braga de, Esteves, Melina Cristina Borges, Nascimento Junior, Daniel Rodrigues do
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2017
País:Brasil
Institución:Universidade Federal do Ceará (UFC)
Repositorio:Repositório Institucional da Universidade Federal do Ceará (UFC)
Idioma:portugués
OAI Identifier:oai:repositorio.ufc.br:riufc/65239
Acceso en línea:http://www.repositorio.ufc.br/handle/riufc/65239
Access Level:acceso abierto
Palabra clave:Gás de folhelho
Faturamento hidráulico
Macroporos
Mineralogia
Argilominerais
Bacia do Parnaíba
Descripción
Sumario:The Pimenteiras Formation records the marine ingression in the Meso/Neo-Devonian of the Parnaíba Basin, and it shales are the main source rock interval for its conventional petroleum system. The aim of this paper is to integrate geological and geochemical data in order to provide the potential on shale gas production of the Pimenteiras Formation, based on the outcrop sampling. Nine depositional facies were identified: shale with ostracods (Fo), micaceous silty-shale (Fm), tabular shale (F), massive fine or very fine sandstones (Af), sandstones with hummocky cross lamination (Ah), interbedded clay-silt couplets with linsen (Hl) and wavy (Hw) hetherolitics, dark siltstone with sulfide levels (S) and clast-supported breccias (Bc), observed on top of the outcrops. Clay minerals dominate the mineralogy, followed by quartz. Weathering processes are evidenced by the high contents of lateritic iron and kaolinite. The scanning electron microscopy allowed to classify the pores into macropores (> 50 μm), and also clusters of organic matter and clay minerals with various habits were seen, highlighting the massive and the vermicular ones. The total organic carbon (TOC) values range from 0.02 to 1.31%. Pyrite crystals occur in the rock with the highest TOC value in response to the anoxic behaviour of the S facies. Additionally, the composition of the clay minerals is dominated by smectites and mixed-layer clay minerals. The preliminary results indicate a prospective difficulty for the hydraulic fracturing due to the major presence of clay minerals. The primary porosity has favourable dimension, but unfavourable geometry. The low thermal maturity and inexpressive TOC values points out to the low potential production. Thus, the rocks of this study are unfavourable for the shale gas production under the current conditions required by the economic market.