Desorption isotherms of flaxseeds (Linum usitatissimum L.) and thermodynamics parameters of the process

Sorption isotherms of flaxseeds were determined by static gravimetric method at temperatures 40; 60; and 80 ºC, over a relative moisture range of 10-95%. Six mathematical models were applied to analyze the experimental data. The modified GAB model showed the best fitting to the experimental data. Th...

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Detalhes bibliográficos
Autores: Valente, Maria da Conceição, Nascimentro, Rafael, Santana, Elza, Faria, Lênio José, Costa, Cristiane Maria
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:Brasil
Recursos:Universidade Federal do Ceará (UFC)
Repositorio:Revista ciência agronômica (Online)
Idioma:inglés
OAI Identifier:oai:periodicos.ufc:article/84891
Acesso em linha:http://periodicos.ufc.br/revistacienciaagronomica/article/view/84891
Access Level:acceso abierto
Palavra-chave:Equilibrium moisture content
Drying
Isosteric heat
Descrição
Resumo:Sorption isotherms of flaxseeds were determined by static gravimetric method at temperatures 40; 60; and 80 ºC, over a relative moisture range of 10-95%. Six mathematical models were applied to analyze the experimental data. The modified GAB model showed the best fitting to the experimental data. The isosteric heat and differential entropy were determined by applying Clausius-Clapeyron and Gibbs-Helmholtz equations, respectively. The isosteric heat and the entropy of desorption isotherm presented similar behavior, with a sharp change in an equilibrium moisture content of 10%. The enthalpy-entropy compensation theory was applied to the isotherms, indicating that they are enthalpy-controlled.