Background values for evaluation of heavy metal contamination in sediments in the Parnaíba River Delta estuary, NE/Brazil

This study establishes regional background levels and upper thresholds (geochemical baseline) for Zn, Cu, Pb, Cr, Mn, and Fe from surface samples and profiles taken in 16 sedimentary environments of the Parnaíba River Delta estuary, NE–Brazil. Three approaches were applied to evaluate metal contamin...

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Detalhes bibliográficos
Autores: Paula Filho, Francisco José de, Marins, Rozane Valente, Lacerda, Luiz Drude de, Peres, Tiago Farias
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:Brasil
Recursos:Universidade Federal do Ceará (UFC)
Repositorio:Repositório Institucional da Universidade Federal do Ceará (UFC)
Idioma:inglés
OAI Identifier:oai:repositorio.ufc.br:riufc/65653
Acesso em linha:http://www.repositorio.ufc.br/handle/riufc/65653
Access Level:acceso abierto
Palavra-chave:Heavy metals
Heavy metals - Background levels
Diffuse sources
Metais pesados
Metais pesados - Contaminação
Forças difusas
Descrição
Resumo:This study establishes regional background levels and upper thresholds (geochemical baseline) for Zn, Cu, Pb, Cr, Mn, and Fe from surface samples and profiles taken in 16 sedimentary environments of the Parnaíba River Delta estuary, NE–Brazil. Three approaches were applied to evaluate metal contamination: normalization to Fe, statistical analysis and sediment quality guidelines or environmental assessment criteria (TEL–PEL). Metal concentrations in sediments ranged from 2.4 to 31 mg Zn kg 1, 1.5 to 48 mg Cu kg 1, 1.3 to 28 mg Pb kg 1, 1.5 to 38 mg Cr kg 1; 145 to 1,356 mg Mn kg 1, and 0.3% to 2.5% for Fe. All metals showed positive correlations with the <0.63 lm sediment fraction, indicating a signif- icant association with rich lithogenic sources of iron oxide–hydroxides. Results suggest a low probability of adverse effects to the local aquatic biota. The background values of the area were lower than those reported for other areas of the northeastern coast of Brazi