Synthesis of Carbolines by Photostimulated Cyclization of Anilinohalopyridines

A general synthetic route to prepare all four carboline regioisomers by photostimulated cyclization of anilinohalopyridines is described. The methodology affords various substituted carbolines in good to excellent yields. In the case of α-carbolines, the S(RN)1 methodology complements previously rep...

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Detalhes bibliográficos
Autores: Laha, Joydev K., Barolo, Silvia Maricel, Rossi, Roberto Arturo, Cuny, Gregory D.
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2011
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/66183
Acesso em linha:http://hdl.handle.net/11336/66183
Access Level:acceso abierto
Palavra-chave:Srn1
Carbolines
Photochemistry
Ring Closure
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descrição
Resumo:A general synthetic route to prepare all four carboline regioisomers by photostimulated cyclization of anilinohalopyridines is described. The methodology affords various substituted carbolines in good to excellent yields. In the case of α-carbolines, the S(RN)1 methodology complements previously reported palladium-catalyzed cyclization approaches.