Application of the multi-standard methodology for calculating 1H NMR chemical shifts

Gauge including atomic orbitals (GIAO)1H NMR chemical shift calculations have been performed for 66 organic compounds at 72 di fferent levels of theory using the multi-standard approach (MSTD) previously developed for 13C NMR. This straightforward computational technique involves the combination of...

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Detalhes bibliográficos
Autores: Sarotti, Ariel Marcelo, Pellegrinet, Silvina Carla
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2012
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/108051
Acesso em linha:http://hdl.handle.net/11336/108051
Access Level:acceso abierto
Palavra-chave:COMPUTATIONAL CHEMISTRY
GIAO
1H NMR CALCULATIONS
MULTI-STANDARD APPROACH
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descrição
Resumo:Gauge including atomic orbitals (GIAO)1H NMR chemical shift calculations have been performed for 66 organic compounds at 72 di fferent levels of theory using the multi-standard approach (MSTD) previously developed for 13C NMR. This straightforward computational technique involves the combination of methanol and benzene as standards. The studied methodology has been shown to predict 1H NMR chemical shifts efficiently at different levels of theory.