Photocatalytic degradation of acridine dyes using anatase and rutile TiO2

The adsorption and photodegradation of acridine orange (AO) and acriflavine (AF) dyes on two mesoporous titania crystalline phases, anatase and rutile, were experimentally studied. Anatase and rutile were characterized by nitrogen adsorption, electron scanning and transmission microscopy, and X-ray...

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Bibliographic Details
Authors: Zubieta, Carolina Edith, Messina, Paula Verónica, Schulz, Pablo Carlos
Format: article
Status:Published version
Publication Date:2012
Country:Argentina
Institution:Consejo Nacional de Investigaciones Científicas y Técnicas
Repository:CONICET Digital (CONICET)
Language:English
OAI Identifier:oai:ri.conicet.gov.ar:11336/95342
Online Access:http://hdl.handle.net/11336/95342
Access Level:Open access
Keyword:ACRIDINE DYES
ADSORPTION
MICROEMULSION
PHOTODEGRADATION
POLLUTION
TITANIA
https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
Description
Summary:The adsorption and photodegradation of acridine orange (AO) and acriflavine (AF) dyes on two mesoporous titania crystalline phases, anatase and rutile, were experimentally studied. Anatase and rutile were characterized by nitrogen adsorption, electron scanning and transmission microscopy, and X-ray diffraction. The adsorption capacity of rutile was higher than that of anatase, while the reverse is observed for photodegradation of both dyes. The adsorption of AF on both adsorbents was higher than that of AO, which was related with the smaller size of AF molecules compared with those of AO, therefore the access of AF to the adsorption sites is favored.