Rhodium-Catalyzed Intramolecular [3+2+2] Cycloadditions between Alkylidenecyclopropanes, Alkynes, and Alkenes
A Rh-catalyzed intramolecular [3+2+2] cycloaddition is reported. The cycloaddition affords synthetically relevant 5,7,5-fused tricyclic systems of type 2 from readily available dienyne precursors. The transformation takes place with moderate or good yields, high diastereoselectivity, and total chemo...
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Detalhes bibliográficos
| Autores: |
Araya, Marisel,
Gulías Costa, Moisés,
Fernández, Israel,
Bhargava, Gaurav,
Castedo Expósito, José Luis,
Mascareñas Cid, José Luis,
López García, Fernando |
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| Formato: | artículo
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| Fecha de publicación: | 2014 |
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| País: | España |
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| Recursos: | Universidad de Santiago de Compostela (USC) |
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| Repositorio: | Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela |
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| Idioma: | inglés |
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| OAI Identifier: | oai:minerva.usc.gal:10347/11966 |
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| Acesso em linha: | http://hdl.handle.net/10347/11966
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| Access Level: | acceso abierto |
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| Palavra-chave: | Materias::Investigación::23 Química::2302 Bioquímica |
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